# Durable and Robust Janus Membranes with Asymmetric Wettability Based on Poly (Vinylidene Fluoride)/Polyvinyl Alcohol for Oil–Water Separation

## TL;DR

This paper presents a durable Janus membrane with asymmetric wettability for efficient oil-water separation, suitable for industrial and environmental applications.

## Contribution

A novel Janus membrane with optimized hydrophobic-hydrophilic layer ratio for robust oil-water separation performance is developed.

## Key findings

- The optimal hydrophobic-to-hydrophilic layer thickness ratio of 4:6 achieved high separation flux and efficiency.
- The membrane maintained stable performance after 50 separation cycles, showing strong durability.
- Separation flux values reached 1888.22 and 1042.66 L m−2 h−1 for oil-water mixtures and water-in-oil emulsions, respectively.

## Abstract

With the acceleration of industrialization, the problems of water resource pollution and shortage caused by oil spills and industrial wastewater discharge have become increasingly severe, posing a major threat to ecological sustainable development. Therefore, efficient oil–water separation technology has become a key breakthrough to alleviate this crisis. In this study, Janus membranes with asymmetric wettability were prepared by layer-by-layer electrospinning. The influence of the thickness ratio between the hydrophobic layer and the hydrophilic layer on the mechanical properties, separation flux, and oil–water mixture efficiency of the Janus membranes was examined, and an optimized membrane configuration was determined: the optimal thickness ratio between hydrophobic and hydrophilic layers was 4:6. Under these conditions, the fracture stress of the fiber membranes reached 99% MPa, the fracture strain was 55.63 ± 4.77%, the separation flux values were 1888.22 and 1042.66 L m−2 h−1 for the oil–water mixture and water-in-oil emulsion, respectively, with the separation efficiencies all exceeding 99%. After 50 cycles of separation for two different oil-in-water emulsions, the separation flux and separation efficiency of the optimal sample remained relatively stable, demonstrating strong practicability. In general, the Janus fiber membranes met the expected requirements, laying a good foundation for future applications in oil–water separation, floating oil collection in water, and other fields.