Influence of Vanadium-Titanium Slag Substitution on Properties and Microstructure of Blast Furnace Slag-Steel Slag-Desulfurization Gypsum Gel System

TL;DR

This study explores how using vanadium-titanium slag in a cement-like material improves its strength and structure.

Contribution

The study introduces a novel approach to enhance vanadium-titanium slag activity and its integration into cementitious systems.

Findings

Mechanical grinding significantly improves the activity index and specific surface area of vanadium-titanium slag.

Replacing blast furnace slag with vanadium-titanium slag enhances the mechanical properties of the cementitious system.

Hydration products like ettringite and C–S–H gels contribute to the system's strength through a stable dendritic structure.

Abstract

The comprehensive utilisation of solid waste is a primary approach to enhancing the utilisation efficiency of mineral resources. However, vanadium-titanium slag has long faced insufficient resource utilisation due to its low activity. To address this issue, this study integrated macro and micro analytical methods to systematically investigate the effect of mechanical grinding on the activity of vanadium-titanium slag, as well as its performance when partially replacing blast furnace slag in the system of slag—converter steel slag-desulfurization gypsum ternary gel system. Additionally, the hydration mechanism of this cementitious system was analysed. The research results indicate that mechanical grinding can significantly improve the activity index of vanadium-titanium slag and increase its specific surface area. Replacing an appropriate amount of slag with vanadium-titanium slag in the slag-steel slag-desulfurization gypsum ternary gel system can effectively enhance the mechanical properties of the cementitious system. The optimal mix proportion of vanadium-titanium slag:slag:steel slag:desulfurization gypsum as 10.5:31.5:42:16 with a water-to-binder ratio of 0.32, under which the 28-day compressive strength of the specimen reached 33.50 MPa. Through multiple microscopic analysis techniques, it was found that in the alkaline environment and sulfate excitation (provided by steel slag hydration and desulfurization gypsum), the cementitious system generates hydration products such as ettringite (AFt), C–S–H, and C–A–S–H gels. Some unreacted vanadium-titanium slag particles are wrapped and intertwined by hydrated calcium silicate (aluminium) gels, forming a stable dendritic structure that provides support for the system’s strength development.

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