Sustainable valorization of marine plastic residues via hydrothermal liquefaction for clean energy recovery
Mahadevan Vaishnavi, S. Raja, Maher Ali Rusho, Tesfaye Barza Zema

TL;DR
This study explores using hydrothermal liquefaction to convert marine plastic waste into clean energy, showing promising results for energy recovery and sustainability.
Contribution
The study introduces an optimized HTL process using diatomaceous earth and aqueous-phase recirculation for marine residue conversion.
Findings
A maximum bio crude yield of 51.6% with a high heating value of 40.3 MJ kg-1 was achieved under optimized conditions.
The DE + AQ configuration improved hydrocarbon content and reduced oxygenation in the products.
Energy-positive operation is possible with elevated aqueous-phase recirculation temperature and heat integration.
Abstract
This study evaluates hydrothermal liquefaction (HTL) of real-world marine pollutant residues (MPR) composed of mixed plastics, organic matter, paper, and textiles. Using diatomaceous earth (DE) catalysis and aqueous-phase (AQ) recirculation, the effects on product yield, composition, and energy recovery were examined. Under optimized conditions (380 °C, 80 min, 10 wt% DE, RR = 6 mL g-1), a maximum bio crude yield of 51.6% with an HHV of 40.3 MJ kg-1 was achieved. Elemental, molecular, and thermal analyses (CHNS, GC–MS, FTIR, TGA) indicated improved hydrocarbon content and reduced oxygenation in the DE + AQ configuration. Net energy ratio (NER) calculations showed that the process can achieve energy-positive operation under conditions of elevated AQ recirculation temperature, highlighting the importance of heat integration. While these results demonstrate effective conversion of…
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Taxonomy
TopicsThermochemical Biomass Conversion Processes · Subcritical and Supercritical Water Processes · Anaerobic Digestion and Biogas Production
