# Fish-Based Biopolymer Complex Coacervate Coating for Improved Paper Oxygen and Water Barrier

**Authors:** Sarah G. Fisher, Zachary Buck, Margaret J. Karim, Jaime C. Grunlan

PMC · DOI: 10.1021/acs.biomac.5c02091 · Biomacromolecules · 2025-11-26

## TL;DR

A new eco-friendly coating made from fish waste improves paper's ability to block oxygen and water, making it a sustainable option for food packaging.

## Contribution

A fully biobased coating using gelatin and DNA from waste improves paper barrier properties significantly.

## Key findings

- Thermally curing the coating reduces water vapor transmission by 83%.
- Oxygen transmission is reduced by 99% compared to uncoated paper.
- The coating is one of the best biobased barrier solutions for paper.

## Abstract

Food packaging is critical to prevent food waste, but most of the packaging used today is not sustainable. Paper-based packaging materials offer a renewable option, but exhibit poor resistance to common permeants such as oxygen, grease, and water vapor. In this work, a complex coacervate coating is prepared from two waste biopolymers, gelatin and DNA, and applied to kraft paper to substantially improve its barrier properties. Thermally curing the coating after deposition decreases the water vapor transmission rate and oxygen transmission rate by 83 and 99%, respectively, relative to uncoated paper. This work represents one of the best fully biobased barrier coatings reported for paper and is a promising option for sustainable food packaging.

## Full-text entities

- **Chemicals:** Water (MESH:D014867), Paper Oxygen (-), oxygen (MESH:D010100)
- **Species:** Actinopterygii (fishes, superclass) [taxon 7898]

## Full text

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## Figures

5 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12806851/full.md

## References

78 references — full list in the complete paper: https://tomesphere.com/paper/PMC12806851/full.md

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Source: https://tomesphere.com/paper/PMC12806851