# Research on thermo-mechanical coupling behavior of plasma-sprayed mullite ceramic coatings on concrete surfaces

**Authors:** Yan Shi, Yaqi Gong, Yuanyi Wang, Jingfeng Sun, Huangkai Sun

PMC · DOI: 10.1371/journal.pone.0337689 · PLOS One · 2026-01-12

## TL;DR

This study examines how plasma-sprayed mullite coatings behave under thermal and mechanical stress on concrete surfaces, offering insights for improving infrastructure durability.

## Contribution

A validated thermo-mechanical coupling model and process optimization framework for plasma-sprayed ceramic coatings on concrete.

## Key findings

- Optimized parameters reduced interfacial residual stress to <50 MPa and porosity to 8.3%.
- SEM-EDS and X-CT analyses showed pore distribution correlates with stress concentration.
- Thermal expansion mismatch was identified as the main cause of coating delamination.

## Abstract

This study systematically investigates the thermo-mechanical coupling behavior of plasma-sprayed mullite ceramic coatings on concrete surfaces through integrated finite element simulation and experimental verification. A three-dimensional thermo-mechanical coupling model was developed on the ANSYS Fluent platform to simulate temperature field distribution, residual stress evolution, and their impacts on interfacial bonding strength during the spraying process. Experimental data calibration confirmed the model accuracy with <5% deviation. Results demonstrate that spraying power and stand-off distance critically influence coating temperature gradients. Optimized parameters reduced interfacial residual stress to <50 MPa while decreasing porosity to 8.3%. SEM-EDS and X-CT analyses revealed the correlation between pore distribution and stress concentration. Thermal expansion coefficient mismatch was identified as the primary cause of interfacial delamination. Process optimization enhanced interfacial bonding strength by 38.7%, establishing a reliable predictive model for coating thermo-mechanical performance. The findings provide theoretical guidance for plasma spraying parameter optimization and establish a validated framework for concrete surface protection coating design. This research advances the fundamental understanding of substrate-coating interactions under thermal-mechanical loads and offers practical solutions for infrastructure durability enhancement.

## Full-text entities

- **Genes:** TGFB1I1 (transforming growth factor beta 1 induced transcript 1) [NCBI Gene 7041] {aka ARA55, HIC-5, HIC5, TSC-5}, TSC1 (TSC complex subunit 1) [NCBI Gene 7248] {aka LAM, TSC}, TSC2 (TSC complex subunit 2) [NCBI Gene 7249] {aka LAM, PPP1R160, TSC4}
- **Diseases:** EDS (MESH:C536196)
- **Chemicals:** Mg (MESH:D008274), MgAl2O4 (MESH:C111130), Ca (MESH:D002118), Fe (MESH:D007501), APS (MESH:D000250), 3Al2O3 2SiO2 (-), silicate (MESH:D017640), Mg2SiO4 (MESH:C503823), O (MESH:D010100), Si (MESH:D012825), alcohol (MESH:D000438), Mullite (MESH:C049037), oil (MESH:D009821), Al (MESH:D000535), epoxy (MESH:D004853)

## Full text

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## Figures

10 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12795364/full.md

## References

20 references — full list in the complete paper: https://tomesphere.com/paper/PMC12795364/full.md

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Source: https://tomesphere.com/paper/PMC12795364