# Unexpected Orange Photoluminescence from Tetrahedral Manganese(II) Halide Complexes with Bidentate Phosphanimines

## TL;DR

This paper reports orange light emission from manganese complexes with a specific ligand, differing from typical green emissions seen in similar compounds.

## Contribution

The study reveals unexpected orange photoluminescence from tetrahedral manganese(II) halide complexes with bidentate phosphanimines.

## Key findings

- The compounds [MnBr2{(PhN=PPh2)CH2}] and [MnI2{(PhN=PPh2)CH2}] show orange emissions under UV light.
- Luminescence decay curves suggest a multiplicity change with excited-state lifetimes in the hundreds of microseconds.
- DFT calculations were used to rationalize the unexpected luminescence behavior.

## Abstract

Manganese(II) halide complexes with the general formula [MnX2{(PhN=PPh2)CH2}], where X is bromine or iodine and (PhN=PPh2)CH2 is the bis-phosphanimine ligand 1,1′-methylenebis-(N,1,1-triphenylphosphanimine), were prepared and isolated. The structure of the two compounds was determined by single-crystal X-ray diffraction, revealing an approximately tetrahedral geometry at the metal centre. Unlike structurally comparable compounds containing phosphine oxides or related [O=P]-donors in the coordination sphere, which commonly show green emissions, solid samples of [MnBr2{(PhN=PPh2)CH2}] and [MnI2{(PhN=PPh2)CH2}] exhibited orange emissions upon irradiation with UV light. The emission spectra resulted excitation-independent. Superimposable steady-state luminescence spectra were collected for both compounds as powders and crystals suitable for X-ray diffraction. The excitation spectra and the ligand→metal antenna effect were affected by the coordinated halide, and only [MnBr2{(PhN=PPh2)CH2}] showed bright luminescence under near-UV irradiation. Either ligand- or metal-centred transitions can account for the observed luminescence, and the luminescence decay curves were consistent with a multiplicity change from the excited to the ground state, with excited-state lifetimes in the range of hundreds of microseconds. Attempts to rationalize the unexpected luminescence were carried out based on DFT calculations.