# Effect of Olive Stone Biomass Ash Filler in Polylactic Acid Biocomposites on Accelerated Weathering Tests

## TL;DR

This study examines how adding ash from olive stones to polylactic acid affects the material's durability and performance under simulated weathering conditions.

## Contribution

The paper introduces a novel use of olive-stone biomass ash as a filler in PLA biocomposites and evaluates its impact on degradation resistance and mechanical properties.

## Key findings

- PLA biocomposites with 3% OBA showed a 50% reduction in tensile strength after 1000 h of weathering.
- Hydroxyl indices increased significantly in biocomposites, reaching up to 5.85 for PLA with 3% OBA.
- A solid-state reaction model was fitted to determine kinetic parameters from TGA data.

## Abstract

Polylactic acid (PLA) is a widely used bio-based polymer, although its application is limited by mechanical brittleness and low thermal resistance. PLA-based biocomposites reinforced with waste materials are gaining attention due to their sustainability, but their durability under degradation conditions remains a key concern. In this work, PLA biocomposites containing 0, 1, and 3% wt. of Olive-stone Biomass Ash (OBA) were manufactured and characterized both (1) after manufacture and (2) after laboratory-accelerated weathering (including UV exposure, heat, and humidity). The results obtained were analyzed to evaluate the influence of ash incorporation on degradation resistance (measured through Carbonyl Indices, CI), mechanical properties (tensile strength), thermal (Thermogravimetric Analysis—Differential Scanning Calorimetry, TGA-DSC), structure (Fourier Transform Infrared Spectroscopy, FT-IR), morphology (Scanning Electron Microscopy, SEM) and appearance (colorimetry and gloss). Key quantitative findings include a 35% reduction in tensile strength for raw PLA after 1000 h weathering exacerbated to 48% and 50% with 1% and 3% OBA incorporation, respectively. Degradation indices showed increased hydroxyl formation, with HI values ranging from 0.38 to 2.80 for PLA, while for biocomposites HI rose up to 5.85 for PLA with 3% OBA. Subsequently, a solid-state reaction was model-fitted from experimental data obtained by means of TGA analysis for determining the kinetic triplet (pre-exponential factor, the activation energy, and the reaction mechanism). Finally, the Acceleration Factor (AF), which combines the effects of radiation, temperature, and humidity to predict long-term material performance, is addressed analytically.