# Pine Bark as a Lignocellulosic Resource for Polyurethane Production: An Evaluation

## TL;DR

This paper investigates using pine bark to create eco-friendly polyurethane foam with improved strength and fire resistance.

## Contribution

A novel method for producing bio-based polyols from pine bark for rigid polyurethane foam is presented.

## Key findings

- Bio-polyols from pine bark at a PC/OH ratio of 3 improved foam compressive strength and thermal insulation.
- Foams with up to 10% pine bark filler showed reduced mechanical properties but lower flammability.
- Bio-polyol-based foams exhibited lower heat release and smoke, indicating better fire safety.

## Abstract

This study explores the potential of pine bark—a highly accessible and underexploited by-product of forestry and food processing—as a renewable raw material for rigid polyurethane (PUR) foam production. Under optimal extraction conditions, water-soluble extractives rich in carbohydrates were isolated from biomass with a yield of 25% and subsequently condensed with propylene carbonate (PC) to produce bio-based polyols. The polyols synthesized at a PC/OH molar ratio ranging from 1 to 5 were incorporated into rigid PUR foam formulations as substitutes for commercial polyether polyols. The foams containing bio-polyols synthesized at a PC/OH ratio of 3 demonstrated the highest compressive strength and thermal insulation performance, exceeding those of the reference material by 30% and 9%, respectively, and exhibited enhanced thermo-oxidative stability. Incorporation of extracted bark up to 10 wt% as a filler in the PUR matrix led to a decrease in mechanical properties to the level of the reference foam and a 19% reduction in thermal insulation capacity, without affecting the closed-cell content. Cone calorimetry revealed that both filled and unfilled bio-polyol-based PUR foams exhibited lower degradation rate, heat release rate, and total smoke release compared with the reference material, indicating reduced flammability and a lower tendency toward fire propagation.