# Site Preferences of Copper and Cobalt Monobenzo Porphyrins in a Trans‐Dibenzo Adsorption Structure on Cu(111)

## TL;DR

The study uses scanning tunneling microscopy to investigate how copper and cobalt porphyrins arrange on a copper surface, revealing site preferences and interaction energies.

## Contribution

The paper provides experimentally derived T-type interaction energies for Cu and Co porphyrins on Cu(111), validated against theoretical predictions.

## Key findings

- Monobenzo porphyrins are enriched at the edges of molecular rows and depleted in the bulk.
- T-type interaction energies for Cu-TPtdBP align well with DFT calculations, while Co-TPtdBP show less agreement.
- Over 50,000 molecules were analyzed to estimate interaction energies using equilibrium considerations.

## Abstract

Using scanning tunneling microscopy, Cu and Co tetraphenyl monobenzo porphyrins are used as probe molecules to better understand the T‐type interactions within well‐ordered islands of Cu and Co tetraphenyl trans‐dibenzo porphyrins on Cu(111). The islands are made up of molecular rows, held together by T‐type interactions between isoindole and phenyl rings of adjacent molecules. The monobenzo molecules are found to be depleted within the bulk of the molecular rows and enriched at the edges terminating the rows. By counting over 50 000 molecules and using equilibrium considerations, the T‐type interaction energies within the trans‐dibenzo islands are estimated and the derived values are compared to values previously calculated with density functional theory, which find very good agreement for Cu‐TPtdBP but less satisfying agreement for Co‐TPtdBP.

We find the monobenzo molecules to be depleted within the bulk of the molecular rows and enriched at the edges, terminating the rows. By counting over 50 000 molecules and using equilibrium considerations, we estimate the T‐type interaction energies within the trans‐dibenzo islands.© 2025 WILEY‐VCH GmbH