# Unifying dynamics of glass-forming liquids by crystallization temperature

**Authors:** Yunhuan Nie, Lijin Wang, Huiming Cao, Pengfei Guan, Ning Xu

PMC · DOI: 10.1093/nsr/nwaf423 · National Science Review · 2025-09-30

## TL;DR

This paper shows that crystallization temperature can unify the complex behavior of different glass-forming liquids.

## Contribution

The paper introduces crystallization temperature as a universal framework to describe diverse dynamics in glass-forming liquids.

## Key findings

- Crystallization temperature links key features of glass-forming liquids like structural relaxation and fragility.
- It connects non-equilibrium glass formers with their equilibrium counterparts.
- The framework applies to super-Arrhenius dynamics and glass transition temperatures.

## Abstract

A crucial question pertaining to the understanding of the elusive glass transition concerns the existence of a universal framework that can describe the dynamics of various glass-forming liquids. Here, we report our achievement of a comprehensive unification of dynamics via the utilization of the crystallization temperature. We provide evidence that the pressure-dependent crystallization temperature links numerous pivotal features of multiple glass-forming liquids, including the super-Arrhenius structural relaxation, dynamical heterogeneity, caging behavior, glass fragility, onset temperature and glass transition temperature. The significant role played by the crystallization temperature reveals the underlying connections between non-equilibrium glass formers and their equilibrium counterparts.

Crystallization temperature provides a universal framework for diverse dynamics of glass-forming liquids.

## Full-text entities

- **Chemicals:** L (MESH:D007930), HARM (-), S (MESH:D013455)

## Full text

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## Figures

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## References

56 references — full list in the complete paper: https://tomesphere.com/paper/PMC12636646/full.md

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Source: https://tomesphere.com/paper/PMC12636646