Enhanced Flame-Retardant Properties of PVDF Using a Multiphase Synergistic Approach with Phytate-Chitosan-Modified Boron Nitride

TL;DR

This paper introduces a new method to enhance the flame resistance of PVDF using modified boron nitride particles.

Contribution

A novel synergistic modification strategy using phytate and chitosan to coat boron nitride for improved flame retardancy in PVDF.

Findings

PVDF composite films with BN@PA-CS showed a 77.83% reduction in peak heat release rate.

The synergistic effect of BN nanosheets and PA-CS significantly improved flame-retardant properties.

The method offers a new approach to enhance the safety of PVDF battery separators.

Abstract

The morphology and composition of inorganic particles play a vital role in controlling the flame-retardant characteristics of polymers. Halogen-free flame-retardant polymers have also become a current research hotspot. Boron nitride (BN), phytic acid (PA), and chitosan (CS), a natural polysaccharide with a nitrogen content of approximately 6.8–7.5%, show great promise as flame retardants owing to their high thermal stability, P-based flame retardancy, and natural polysaccharide properties, respectively. In this study, BN (BN@PA-CS) particles coated with PA and CS were designed and prepared via a facile modification strategy. The effect of BN@PA-CS on the mechanical and flame-retardant properties of polyvinylidene fluoride (PVDF) was further investigated, and it was found that both characteristics were improved. Compared to pure PVDF, the PVDF composite films exhibited a significantly lower peak heat release rate and total heat release. With a BN@PA-CS content of 20%, the peak was the lowest at 18.25 W/g, corresponding to a decrease of 77.83%. This phenomenon may be attributed to the synergistic effect of the BN nanosheets and PA-CS in the BN@PA-CS particles. This work describes a facile and effective method of modifying the morphology and composition of inorganic particles, thereby controlling the properties of polymers, and provides a new approach to improving the safety of PVDF battery separators.

Figures