# Mitigating Composition Variability in Post-Industrial PC/ABS Recycling via Targeted Compatibilization

## TL;DR

This paper explores how to improve the recycling of automotive plastic scraps by using a specific additive to enhance material performance.

## Contribution

The study introduces a targeted compatibilization strategy using E-MA-GMA to optimize recycled PC/ABS blends for automotive applications.

## Key findings

- E-MA-GMA terpolymer significantly improves impact resistance in PC-rich recycled blends.
- A response surface model predicts impact performance across varying polymer compositions and additive content.
- Compatibilization reduces degradation and enhances compatibility in PC/ABS recycling.

## Abstract

The growing demand for sustainable solutions in the plastics industry has highlighted the need to reintroduce post-industrial polymer waste into high-performance applications. This study focuses on the mechanical recycling of automotive scraps containing variable proportions of polycarbonate (PC), acrylonitrile–butadiene–styrene (ABS), and a commercial PC/ABS blend. After determining the composition of two representative batches, a screening of seven commercial compatibilizers and impact modifiers was performed to improve impact strength. Among them, an ethylene–methyl acrylate–glycidyl methacrylate (E-MA-GMA) terpolymer was identified as the most effective additive. Its influence was further investigated through a mixture design approach, varying the composition of the three polymer phases and the additive content (0–10 wt.%). The resulting response surface model revealed a significant increase in impact resistance in PC-rich formulations with increasing E-MA-GMA content, while ABS and PC/ABS showed more complex trends. Rheological, mechanical, and thermal analyses supported the observed behavior, suggesting improved matrix compatibility and reduced degradation during processing. The proposed model enables the prediction of impact performance across a wide range of compositions, offering a practical tool for the optimization of recycled blends. These findings support the potential of targeted compatibilization strategies for closed-loop recycling in the automotive sector.