# Enhanced phosphorus elimination from aquatic systems employing modified granular waterworks derived sludge composite materials: Mechanistic evaluation and process optimization

## TL;DR

A new composite material made from water treatment sludge effectively removes phosphorus from water, offering a sustainable and low-cost solution for pollution control.

## Contribution

The novel GT La-WDS composite material demonstrates superior phosphate adsorption and extended performance in constructed wetlands.

## Key findings

- The composite achieved a phosphate adsorption capacity of 20.11 mg/g at pH 4.
- Dynamic column tests showed prolonged breakthrough and exhaustion times with increased bed height.
- Effluent phosphate concentrations remained below regulatory limits for over 588 hours.

## Abstract

A novel granular waterworks-derived sludge composite (GT La-WDS) was synthesized via green and low-carbon hydrothermal carbonization combined with a calcination-free granulation method, demonstrating exceptional phosphate adsorption performance and potential as constructed wetland filler. Comprehensive characterization (SEM, XRF, BET, FTIR, XRD) revealed its hierarchical porous morphology, chemical composition, and hydroxyl/ligand-functionalized surfaces. Optimal phosphate adsorption capacity (20.11 mg/g) was achieved at pH 4, with adsorption mechanisms dominated by ligand substitution and formation of inner-sphere complexes, as supported by quasi-second-order kinetic modeling and Freundlich isotherm conformity. Dynamic column tests showed prolonged breakthrough (from 168 h to 432 h) and exhaustion times (from 588 h to 2088 h) with increasing bed heights (10 cm to 30 cm), achieving total adsorption capacities of 9.276 mg/g. Effluent phosphate concentrations remained below 0.5 mg/L (Chinese National Effluent Standard Class 1B) for 588 h, with sustained removal efficiency over 2088 h, indicating remarkable longevity. This sludge-derived composite presents a cost-effective solution for phosphorus sequestration, offering dual benefits of eutrophication mitigation and sustainable sludge valorization, with particular relevance to low-carbon constructed wetland systems.