# Seawater-resistant emulsified epoxy resin for effective sand control in unconsolidated sandstone oil reservoir

**Authors:** Chenyang Tang, Wei Zheng, Yufei He, Shaobing Cai, Juanzhe Jiang, Yue Pan, Ke Li, Xiaoxia Shang, S. Shanmugan, S. Shanmugan, S. Shanmugan

PMC · DOI: 10.1371/journal.pone.0335819 · PLOS One · 2025-10-31

## TL;DR

A new epoxy resin system was developed to control sand production in oil wells, even in high-salinity environments.

## Contribution

The novel nonionic emulsifying curing agent enables salinity tolerance up to 3.8 × 10⁴ mg/L in emulsified epoxy resins.

## Key findings

- Consolidated cores achieved compressive strength over 3 MPa and permeability retention above 75% after curing.
- The resin system maintained stability after 30-day immersion in kerosene, 10% HCl, and formation water.
- An optimal formulation was identified with 16% epoxy resin, 24% emulsified curing agent, and other additives.

## Abstract

Sand production in oil wells is recognized as a persistent challenge during oilfield development, adversely affecting well productivity and operational stability. Chemical sand control methods, particularly resin-based sand consolidation, are considered a promising solution due to their operational simplicity and effectiveness. However, conventional emulsified resins are known to be highly sensitive to high-salinity environments, which can lead to emulsion destabilization and reduced consolidation strength. To address this limitation, a novel emulsified epoxy resin system was developed in this study using a nonionic emulsifying curing agent—fatty amine poly(epoxy ethyl ether)—by which salinity tolerance is significantly enhanced, supporting dilution water salinity up to 3.8 × 10⁴ mg/L. Through single-factor experiments, an optimal formulation was identified as 16% epoxy resin, 24% emulsified curing agent, 1% coupling agent, and 5.6% stabilizer. The molecular structure of the emulsified resin and the stability of the cured matrix were thoroughly characterized. The effects of curing temperature, time, sand particle size, and stabilizer dosage on compressive strength and permeability were systematically evaluated. It was demonstrated that after being cured at 80 °C for 12 hours, the consolidated cores achieved a compressive strength exceeding 3 MPa with permeability retention above 75%. Furthermore, the consolidated cores were shown to exhibit excellent long-term stability, maintaining their mechanical and flow properties after 30-day immersion in kerosene, 10% HCl, and formation water. This study bridges a critical research gap in high-salinity applications of water-based resin emulsions and provides a robust technical solution for sand control in challenging reservoir environments.

## Linked entities

- **Chemicals:** epoxy resin (PubChem CID 3559), HCl (PubChem CID 313)

## Full-text entities

- **Chemicals:** water (MESH:D014867), HCl (MESH:D006851), fatty amine poly(epoxy ethyl ether) (-), epoxy resin (MESH:D004853), resin (MESH:D012116)

## Full text

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## Figures

19 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12578148/full.md

## References

36 references — full list in the complete paper: https://tomesphere.com/paper/PMC12578148/full.md

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Source: https://tomesphere.com/paper/PMC12578148