# Design and Evaluation of a Thermally Stable and Salt-Resistant Amphoteric Surfactant-Based Fracturing Fluid for High-Performance Hydraulic Stimulation

**Authors:** Baoge Cao, Linlin Li, Fanchen Ma

PMC · DOI: 10.3390/polym17202741 · Polymers · 2025-10-14

## TL;DR

A new amphoteric surfactant-based fracturing fluid was developed to improve oil and gas extraction in harsh reservoir conditions.

## Contribution

The novel silane-grafted amphoteric surfactant design enables superior thermal and salt resistance compared to conventional surfactants.

## Key findings

- The fracturing fluid retained over 96.7% viscosity after 72 hours at 150 °C and 20 wt% NaCl.
- Field tests showed 81% and 133% increases in oil and gas production, respectively.
- The fluid improved wettability and oil flow by reducing contact angles on sandstone surfaces.

## Abstract

As oil and gas exploration advances, the development of deep, low-permeability, high-temperature, and high-salinity reservoirs poses increasing challenges. To address this, a novel amphoteric surfactant (TASS) was synthesized via free radical polymerization, and a high-performance water-based fracturing fluid system was developed. The system exhibited excellent thermal and salt resistance, with viscosity decreasing by less than 3.3% after 72 h at 150 °C and 20 wt% NaCl. It demonstrated clear shear-thinning behavior and strong elasticity. Interfacial activity tests showed that increasing NaCl concentrations reduced interfacial tension from 28.5 to 24.3 mN/m, while the contact angle on sandstone surfaces decreased significantly, indicating enhanced wettability and oil flow. Field applications further confirmed its effectiveness, with oil and gas production increasing by 81% and 133%, respectively, and a payback period of around 10 days. These results highlight the TASS fracturing fluid as a promising solution for stimulation in complex reservoirs. Unlike conventional betaine-type VES, the silane-grafted amphoteric design of TASS ensures viscosity retention at 220 °C and 25 wt% salinity.

## Linked entities

- **Chemicals:** NaCl (PubChem CID 5234)

## Full-text entities

- **Chemicals:** oil (MESH:D009821), Amphoteric Surfactant (-), Salt (MESH:D012492), silane (MESH:D012821), NaCl (MESH:D012965), water (MESH:D014867), betaine (MESH:D001622)

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## References

28 references — full list in the complete paper: https://tomesphere.com/paper/PMC12566661/full.md

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Source: https://tomesphere.com/paper/PMC12566661