# Experimental Study of Glow Discharge Polymer Film Ablation with Shaped Femtosecond Laser Pulse Trains

## TL;DR

This study shows how shaping femtosecond laser pulses improves the precision and efficiency of drilling microholes in glow discharge polymer films.

## Contribution

The study establishes the first demonstration of temporal pulse shaping's critical role in femtosecond laser drilling of GDP films.

## Key findings

- Shaped femtosecond laser pulses produce smaller and more uniform microholes in GDP films.
- Pulse shape and focusing position significantly influence ablation efficiency and processing quality.
- Temporal pulse shaping offers a new method to optimize laser parameters for precision polymer film processing.

## Abstract

A glow discharge polymer (GDP) has unique physical properties—transparency, brittleness, and hardness—that pose challenges for traditional mechanical machining techniques. We have investigated the microhole fabrication of GDP films using shaped femtosecond laser pulses to study the influence of pulse shape, delay between subpulses, and focusing position on processing precision and efficiency. By precisely controlling pulse characteristics, such as duration, energy, and subpulse intervals, the efficiency, hole morphology, and processing quality were significantly improved. The experimental results demonstrated that femtosecond lasers with subpulses produce smaller and more uniform microholes compared to transform-limited pulses. Furthermore, both the pulse shape and focusing position of the laser were found to further influence ablation efficiency. This study establishes, for the first time, the critical role of temporal pulse shaping in optimizing the femtosecond laser drilling of GDP films, which provides valuable information on optimizing femtosecond laser parameters for precision processing of polymer films and advances the potential for microhole fabrication in industrial applications.