# Comprehensive analysis and effective treatment of plugging in shale gas wells: From composition identification to removal agent optimization

**Authors:** Yujia Xiong, Jun Xin, Chao Su, Lei Liang, Qinghua Xiao, Haifeng Ye, Zilai Mei

PMC · DOI: 10.1371/journal.pone.0334495 · PLOS One · 2025-10-16

## TL;DR

This study investigates and addresses plugging issues in shale gas wells in southern Sichuan, China, by analyzing the composition of plugs and developing effective removal agents.

## Contribution

The paper introduces specialized removal agents optimized for different types of plugging materials in shale gas wells.

## Key findings

- Plugging materials are mainly inorganic, including iron-based impurities and mineral scale deposits.
- An organic composite acid-organic solvent system achieved 98% dissolution efficiency for iron oxide plugs.
- CDTA and DTPA-based agents were effective for iron sulfide and barium sulfate/calcium carbonate deposits, respectively.

## Abstract

With the extensive exploitation of shale gas fields in southern Sichuan, China, the Weiyuan Area – a key production zone within this region – has experinced a growing gas well plugging problem, which significantly hampers production efficiency. This study presents a comprehensive analysis of plugging problems in this area. Plugging samples were obtained from typically affected gas wells and subjected to a suite of analytical techniques. Results indicated that plugging materials were predominantly inorganic, primarily comprising iron-based impurities and mineral scale deposits, while organic components—present in minor proportions—primarily composed of long-chain alkanes. The formation of these plugs is attributed to downhole corrosion, high-salinity formation water, and complex chemical interactions occurring within the wellbore. In response, specialized plugging removal agents were developed: an organic composite acid-organic solvent system achieved up to 98% dissolution efficiency for iron oxide-dominated plugs; a chelating agent based on CDTA was optimized for iron sulfide-based plugging; and the DTPA-based system exhibited superior dissolution efficiency for barium sulfate/calcium carbonate scale deposits. This research provides a scientific basis for effectively mitigating plugging issues in comparable shale gas fields.

## Linked entities

- **Chemicals:** iron oxide (PubChem CID 123289), iron sulfide (PubChem CID 160957), barium sulfate (PubChem CID 24414), calcium carbonate (PubChem CID 10112), CDTA (PubChem CID 10213), DTPA (PubChem CID 3053)

## Full-text entities

- **Chemicals:** iron (MESH:D007501), alkanes (MESH:D000473), water (MESH:D014867), barium sulfate (MESH:D001466), iron oxide (MESH:C000499), calcium carbonate (MESH:D002119), DTPA (MESH:D004369), iron sulfide (MESH:C022597), CDTA (MESH:C005390)

## Full text

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## Figures

15 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12530535/full.md

## References

29 references — full list in the complete paper: https://tomesphere.com/paper/PMC12530535/full.md

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Source: https://tomesphere.com/paper/PMC12530535