Calorimetric Studies of the Silver-Titanium System

TL;DR

This study experimentally investigates the thermodynamic properties of silver-titanium alloys using calorimetry and structural analysis to improve understanding of their phase behavior.

Contribution

The use of titanium hydride in synthesizing Ag-Ti alloys and reoptimization of the Ag-Ti phase diagram using new calorimetric data.

Findings

DSC determined characteristic temperatures of the Ag0.43Ti0.57 alloy.

High-temperature drop calorimetry measured mixing and formation enthalpies in the Ag-Ti system.

The Ag-Ti phase diagram was reoptimized using new experimental data.

Abstract

Alloys from the Ag-Ti system are extremely promising and offer the possibility of versatile applications owing to their attractive properties. However, due to the experimental difficulties caused, among others, by the significant difference in melting points of the components, most of the information on the thermodynamic properties available in the literature has been obtained by computer methods. Therefore, the main aim of this work is to extend the current knowledge about the experimentally determined thermodynamic properties of selected alloys from the Ag-Ti system. Within the scope of this work, calorimetric studies were carried out using Differential Scanning Calorimetry (DSC) and high-temperature drop calorimetry measurements. The first of the aforementioned methods was used to determine the characteristic temperature of the Ag0.43Ti0.57 alloy synthesized by mechanical alloying. Using titanium hydride instead of titanium for the preparation of alloys from the Ag-Ti system has not yet been reported in the literature. This paper presents a complete structural characterization (SEM, XRD studies) of the above alloy produced by this method. The second technique was applied to ascertain the mixing enthalpy change in the alloys in the composition range between xTi = 0.02–0.226, and for the measurements of the formation enthalpy of the AgTi intermetallic phase. Based on the calorimetric results obtained in this study, along with the relevant thermodynamic data from the literature, the Ag-Ti phase diagram was reoptimized.

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