# A more accurate estimation of the specific surface area of TiO2 nanoparticles capped with organic ligands

**Authors:** Masahiko Sagawa, Shohei Yamashita, Yohei Okada

PMC · DOI: 10.1039/d5na00732a · Nanoscale Advances · 2025-08-06

## TL;DR

This paper shows how using F− ions can remove organic coatings from TiO2 nanoparticles to better measure their surface area.

## Contribution

A novel method using F− ions to strip organic ligands for accurate surface area estimation of TiO2 nanoparticles.

## Key findings

- F− ions effectively remove organic ligands from TiO2 nanoparticle surfaces.
- N2 adsorption–desorption isotherms with the BET model provide more accurate surface area measurements after ligand removal.

## Abstract

The specific surface area is important information for nanoparticles. Herein, we demonstrate that treatment with F− ions can strip organic ligands from the surface of TiO2 nanoparticles, which enables a more accurate estimation of the specific surface area using N2 adsorption–desorption isotherms in conjunction with the Brunauer–Emmett–Teller model.

F− ions can strip organic ligands from the surface of TiO2 nanoparticles, which enables a more accurate estimation of the specific surface area using N2 adsorption–desorption isotherms in conjunction with the Brunauer–Emmett–Teller model.

## Linked entities

- **Chemicals:** TiO2 (PubChem CID 26042), N2 (PubChem CID 947)

## Full-text entities

- **Chemicals:** N2 (MESH:D009584), F (MESH:D005461), TiO2 (MESH:C009495)

## Full text

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## Figures

5 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12337766/full.md

## References

27 references — full list in the complete paper: https://tomesphere.com/paper/PMC12337766/full.md

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Source: https://tomesphere.com/paper/PMC12337766