# Experimental Investigation of Steel Bar Corrosion in Recycled Plastic Aggregate Concrete Exposed to Calcium Chloride Cycles

**Authors:** Federica Zanotto, Alice Sirico, Andrea Balbo, Patrizia Bernardi, Sebastiano Merchiori, Vincenzo Grassi, Beatrice Belletti, Cecilia Monticelli

PMC · DOI: 10.3390/ma18143361 · 2025-07-17

## TL;DR

This study investigates how using recycled plastic in concrete affects steel bar corrosion when exposed to calcium chloride cycles.

## Contribution

The study provides new insights into the electrochemical behavior of rebars in concrete with recycled plastic aggregates under chloride exposure.

## Key findings

- Concrete with plastic granules offers good protection against rebar corrosion in low chloride environments.
- Modified concrete shows improved post-cracking behavior and enhanced ductility despite reduced compressive strength.
- Electrochemical methods like EIS and polarization curves effectively monitor corrosion behavior.

## Abstract

Recycling plastics waste into concrete represents one of the possible approaches for its valorization, offering both economic and environmental benefits. Although numerous studies have explored the mechanical properties of concrete with plastics waste, its durability performance remains largely unexplored. In this context, this study aims to assess the electrochemical behavior of rebars embedded in reinforced concrete modified by partially replacing natural aggregates with recycled plastics, comparing their behavior to that of conventional concrete. The corrosion of reinforcing steel bars was evaluated by wet and dry cycles (w/d) in calcium chloride solutions, monitoring corrosion potential and potentiostatic polarization resistance, and recording electrochemical impedance spectroscopy (EIS) and polarization curves. In addition, the chloride diffusion tendency and the mechanical performances were assessed in unreinforced samples. The findings indicate that in environments with lower chloride concentrations, concrete with plastic granules provides good protection against rebar corrosion. Although the mechanical results of the studied mixes confirmed that incorporating plastic granules as aggregates in the concrete matrix causes a reduction in compressive strength, as known in the literature, the modified concrete also exhibits improved post-cracking behavior, resulting in enhanced ductility and fracture toughness.

## Linked entities

- **Chemicals:** calcium chloride (PubChem CID 5284359)

## Full-text entities

- **Chemicals:** Steel Bar (-), chloride (MESH:D002712), steel (MESH:D013232), Calcium Chloride (MESH:D002122)

## Figures

17 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12297927/full.md

---
Source: https://tomesphere.com/paper/PMC12297927