Sulfonated Biopolymer Derived from Wheat Straw for the Recovery of Au(III)

TL;DR

This paper shows that modified wheat straw can efficiently recover gold from water, offering a low-cost and effective solution.

Contribution

The novel use of sulfuric acid-treated wheat straw for Au(III) adsorption and its detailed mechanistic insights are presented.

Findings

Modified wheat straw achieved 99% Au(III) adsorption efficiency at 1.0 mol/L acid concentration.

Adsorption capacity increased 4.5 times with higher Au(III) concentration.

Kinetic studies suggest chemisorption as the rate-limiting step.

Abstract

This study investigates the potential of sulfuric acid modified wheat straw, polysaccharide-rich agricultural byproduct, as a low-cost adsorbent for the selective adsorption of Au(III) ions from aqueous solutions. The wheat straw was treated with concentrated sulfuric acid to enhance its surface properties and functional groups, particularly sulfonic and oxygen-containing functional groups. Adsorption experiments were performed under various conditions, including acid concentrations ranging from 1.0 to 3.0 mol/L, contact times from 1 to 6 h, and initial Au(III) concentrations of 60.36, 90.0, and 150.0 mg/L. The highest adsorption efficiency, 99.0%, was achieved at an acid concentration of 1.0 mol/L. Furthermore, it was determined that an increase in the initial Au(III) concentration from 60.36 mg/L to 150.0 mg/L resulted in a 4.5 times increase in maximum adsorption capacity under optimal conditions. Kinetic modeling revealed that the adsorption process followed pseudo-second order kinetics, suggesting chemisorption as the rate-limiting step. Characterization techniques such as SEM/EDS, XRD, BET and XPS confirmed structural modification, surface sulfonating, and the successful adsorption and reduction of Au(III) to elemental gold (Au0) on the modified straw surface. This work demonstrates that modified wheat straw is a promising, effective, and low cost for the recovery of gold from low-concentration solutions and provides insight into the adsorption and reduction mechanisms at the molecular level.

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