# Mid-IR standoff measurement of ageing-related spectroscopic changes in bitumen in the 6 µm (1700 cm−1) region. Part 1: Measurement strategy and instrument design principles

## TL;DR

This paper outlines a method to measure bitumen aging using mid-infrared spectroscopy, focusing on carbonyl bonds and overcoming atmospheric interference.

## Contribution

A novel standoff measurement strategy and instrument design for detecting bitumen aging via mid-IR spectroscopy.

## Key findings

- A measurement strategy was proposed to detect carbonyl bonds in bitumen at 6 µm despite atmospheric water vapor absorption.
- An instrument design was described using four laser wavelengths to measure reflectivity and aging markers.
- The 3.8 µm wavelength was identified as a stable reference unaffected by bitumen aging.

## Abstract

A strategy is described to make in-situ measurements of a spectroscopic marker of ageing in bitumen binders used on asphalt-paved roads. Oxidation of bitumen at the surface increases the number of carbonyl (C=O) bonds, and this can be measured in the 6 μm region (1700 cm−1) of the mid-infrared. A measurement strategy is proposed to make standoff measurements of surface reflectivity in this region, despite the challenge presented by numerous strong absorption lines from atmospheric water vapour within the optical path. An instrument design is described to make measurements at 4 discrete laser wavelengths, namely 1593.0, 1641.4 and 1731.3 cm−1 (around 6 µm) and at 2633.6 cm−1 (3.8 µm), the first 3 responding to carbonyl absorption and the fourth acting as a spectral reference that is substantially unaffected by ageing. Part 2 of this paper describes the implementation of such an instrument and its experimental performance.