# Biomass-Based Nanocomposites of Polydithioacetals Derived from Vanillin with Cellulose Nanocrystals: Synthesis, Thermomechanical and Reprocessing Properties

## TL;DR

Scientists created a new type of eco-friendly material using vanillin and cellulose that is strong, heat-resistant, and can be recycled.

## Contribution

A novel synthesis method for bio-based nanocomposites with enhanced thermomechanical and reprocessing properties.

## Key findings

- Nanocomposites with 20 wt% CNCs showed over tenfold increase in modulus and threefold increase in tensile strength.
- The material exhibits excellent reprocessing properties due to dynamic dithioacetal bonds.
- CNCs were finely dispersed in the polymer matrix, enhancing overall performance.

## Abstract

Bio-based polydithioacetal nanocomposites were synthesized to address the critical need for materials that simultaneously achieve enhanced thermomechanical properties and excellent reprocessing capabilities. Using vanillin and cellulose nanocrystals (CNCs) as starting materials, linear polydithioacetals (PDTAs) were prepared via acid-catalyzed polycondensation of vanillin with various dithiols including 1,6-hexanedithiol, 1,10-decanedithiol, 3,6-dioxa-1,8-octanedithiol and 2,2′-thiodiethanethiol. These PDTAs were then crosslinked with a diepoxide (i.e., diglycidyl ether of bisphenol A, DGEBA) via the reaction of phenolic hydroxyl groups of PDTAs with epoxide groups of DGEBA. To create the nanocomposites, cellulose nanocrystals (CNCs) were surface-functionalized with thiol groups and then incorporated as the reinforcing nanofillers of the networks. The results of morphological observation showed that the fine dispersion of CNCs in the polymer matrix was attained. Owing to the incorporation of CNCs, the nanocomposites displayed improved thermomechanical properties. Compared to the network without CNCs, the nanocomposite containing 20 wt% CNCs exhibited an increase of more than tenfold in modulus and threefold in tensile strength. In addition, the nanocomposites exhibited excellent reprocessing properties, attributable to the dynamic exchange of dithioacetal bonds. This work presents a promising strategy for developing bio-based nanocomposites that have not only improved thermomechanical properties but also excellent reprocessing (or recycling) properties.