Open-Pore Skeleton Prussian Blue as a Cathode Material to Achieve High-Performance Sodium Storage

TL;DR

A new Prussian blue cathode material with an open-pore structure improves sodium-ion battery performance by enhancing rate and cycling stability.

Contribution

The open-pore skeleton Prussian blue (PB-3) is synthesized using a template method to improve sodium storage performance.

Findings

PB-3 shows a reversible capacity of 92 mAh g−1 at 2000 mA g−1.

PB-3 retains 90.2% capacity after 600 cycles at 500 mA g−1.

Ex situ XRD confirms the stabilized lattice structure enhances cycling performance.

Abstract

Prussian blue and its analogs (PBAs), considered potential cathode materials for sodium-ion batteries (SIBs), still confront multiple challenges. For example, many defect vacancies and high crystal water content are generated during the fast crystallization of PBAs, impairing the rate performance. The stress accumulation during Na+ insertion/extraction destabilizes the lattice framework and then damages the electrochemical performance. Herein, iron-based Prussian blue with an open-pore skeleton structure (PB-3) is prepared using a facile template method which employs PVP and sodium citrate to control the crystallization rate and adjust the particle morphology. The prepared materials exhibit excellent kinetic properties and are conducive to mitigate the volume changes during ion insertion/extraction processes. PB-3 electrode not only exhibits a superior rate performance (92 mAh g−1 reversible capacity at 2000 mA g−1), but also presents superior cycling performance (capacity retention remained at 90.2% after 600 cycles at a current density of 500 mA g−1). The highly reversible sodium ion insertion/extraction mechanism of PB-3 is investigated by ex situ XRD tests, which proves that the stabilized lattice structure can enhance the long cycling performance. In addition, the considerable capacitance contributes to the rate performance. This study provides valuable insights for the subsequent development of high-performance and stable cathodes for SIBs.

Figures