# Graphene-driven correlated electronic states in one dimensional defects within WS2

**Authors:** Antonio Rossi, John C. Thomas, Johannes T. Küchle, Elyse Barré, Zhuohang Yu, Da Zhou, Shalini Kumari, Hsin-Zon Tsai, Ed Wong, Chris Jozwiak, Aaron Bostwick, Joshua A. Robinson, Mauricio Terrones, Archana Raja, Adam Schwartzberg, D. Frank Ogletree, Jeffrey B. Neaton, Michael F. Crommie, Francesco Allegretti, Willi Auwärter, Eli Rotenberg, Alexander Weber-Bargioni

PMC · DOI: 10.1038/s41467-025-60993-x · 2025-07-01

## TL;DR

The paper shows how graphene influences the formation of special electronic states in defects within WS2, a two-dimensional material.

## Contribution

The study demonstrates that graphene's charge transfer is critical for forming Tomonaga-Luttinger liquid states in one-dimensional defects of WS2.

## Key findings

- Graphene induces charge transfer into one-dimensional metal defects in WS2.
- Tomonaga-Luttinger liquid behavior is observed in these defects when supported by graphene.
- Electronic correlations and band structure are visualized using advanced microscopy techniques.

## Abstract

Tomonaga-Luttinger liquid (TLL) behavior in one-dimensional systems has been predicted and shown to occur at semiconductor-to-metal transitions within two-dimensional materials. Reports of one-dimensional defects hosting a Fermi liquid or a TLL have suggested a dependence on the underlying substrate, however, unveiling the physical details of electronic contributions from the substrate require cross-correlative investigation. Here, we study TLL formation within defectively engineered WS2 atop graphene, where band structure and the atomic environment is visualized with nano angle-resolved photoelectron spectroscopy, scanning tunneling microscopy and spectroscopy, and non-contact atomic force microscopy. Correlations between the local density of states and electronic band dispersion elucidated the electron transfer from graphene into a TLL hosted by one-dimensional metal (1DM) defects. It appears that the vertical heterostructure with graphene and the induced charge transfer from graphene into the 1DM is critical for the formation of a TLL.

Tomonaga-Luttinger liquid behavior has been observed within 1D defects in transition metal dichalcogenides. Here, using complementary experiments and engineered defects, the authors demonstrate the importance of graphene as a substrate and its role in the formation of this quasiparticle excitation in 2D WS2.

## Full-text entities

- **Chemicals:** TLL (-), Graphene (MESH:D006108)

## Figures

5 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12215652/full.md

---
Source: https://tomesphere.com/paper/PMC12215652