# Development of Lightweight Thermoplastic Acrylic PMMA Composites and Characterization of Their Mechanical Properties

## TL;DR

This study develops lightweight PMMA composites with optimized mechanical properties by adjusting chemical ratios and testing their performance in fiber composites.

## Contribution

A novel approach to optimizing PMMA resin composition for structural composites through BPO/DMA ratio adjustments and polynomial regression modeling.

## Key findings

- PMMA resins achieved tensile strengths up to 66 MPa with induction times between 100 and 207 minutes.
- Optimized PMMA composites in UD laminates reached 1244 MPa tensile strength, comparable to epoxy-based composites.
- PMMA composites showed 64% higher fiber volume fraction than typical glass/epoxy composites.

## Abstract

The effects of benzoyl peroxide (BPO) and dimethylaniline (DMA) composition on the induction time and the tensile strength of thermoplastic acrylic (PMMA) resins have been investigated in this study. Eighteen resin formulations were prepared with different BPO/DMA ratios (2.0–9.5) and DMA contents (0.28–0.65 mol%), and it was observed that tensile strengths reached up to 66 MPa, and induction times (ITs) ranged from 100 to 207 min. Higher BPO/DMA ratios improved tensile strength but shortened IT, while greater DMA content accelerated curing. Polynomial regression models were successfully established, i.e., a third-order equation for the strength and a second-order equation for the IT, based on the BPO/DMA ratio and DMA content to identify the optimal formulation to balance the strength and the IT time. Two selected formulations, P-4-0.5 and P-3-0.3, were applied in vacuum-assisted resin infusion of glass fiber composites. The best-performing unidirectional (UD) laminate achieved a tensile strength of 1244 MPa. As regards ±45° biaxial (BX45) laminates, they exhibited a tensile strength of 124 MPa and a failure strain of 9.02%, which, while lower than that of epoxy, indicates competitive performance. These results demonstrate that the resin was well infused, resulting in 64% higher fiber volume fraction than typical infused glass/epoxy composites, and compositionally optimized PMMA resins can deliver epoxy-comparable strength and enhance damage tolerance in structural composite applications.