# Microwave-assisted hydrothermal synthesis of amino acid-loaded Cu2O hybrid particles for CO2 reduction electrocatalysis

**Authors:** Yuki Tsuda, Mizuki Irizawa, Saki Fukuma, Minami Kato, Takao Gunji, Kazuki Yoshii, Nobuhiko Takeichi

PMC · DOI: 10.1039/d5ra02252e · RSC Advances · 2025-05-15

## TL;DR

Researchers made Cu2O particles with amino acids using microwave-assisted methods to improve CO2 reduction, especially for producing ethylene.

## Contribution

A novel microwave-assisted synthesis method for amino acid-loaded Cu2O particles that enhances CO2 electrocatalysis.

## Key findings

- Amino acid-loaded Cu2O particles show varied selectivity in CO2 electrolysis products.
- l-histidine-loaded Cu2O particles achieved 18.5% faradaic efficiency for ethylene production.

## Abstract

Amino acid-loaded Cu2O hybrid particles were synthesized via microwave-assisted hydrothermal reaction for efficient CO2 reduction. The amino acid-loaded Cu2O particles exhibited different selectivities in the CO2 electrolysis products depending on type of loaded amino acid. Notably, as compared to amino acid-unloaded Cu2O particles, the l-histidine-loaded Cu2O hybrid particles exhibited an improvement of faradaic efficiency to 18.5% toward ethylene production.

Amino acid-loaded Cu2O hybrid particles were synthesized via microwave-assisted hydrothermal reaction for efficient CO2 reduction.

## Linked entities

- **Chemicals:** CO2 (PubChem CID 280), ethylene (PubChem CID 6325), l-histidine (PubChem CID 6274), Cu2O (PubChem CID 10313194)

## Full-text entities

- **Diseases:** weight loss (MESH:D015431)
- **Chemicals:** formic acid (MESH:C030544), Pt (MESH:D010984), H2 (MESH:D006859), hydrocarbons (MESH:D006838), Al (MESH:D000535), Amino acid (MESH:D000596), alcohols (MESH:D000438), silver chloride (MESH:C037548), methanol (MESH:D000432), C6H9N3O2 (MESH:D006639), carbon (MESH:D002244), Gly (MESH:D005998), CH4 (MESH:D008697), Nafion (MESH:C040402), C6H12O6 (MESH:D005947), ethanol (MESH:D000431), imidazole (MESH:C029899), Cu2O (MESH:C000520), Cit (MESH:D002956), KCl (MESH:D011189), KHCO3 (MESH:C026329), water (MESH:D014867), metal (MESH:D008670), C9H11NO2 (MESH:D010649), O (MESH:D010100), C5H10N2O3 (MESH:D005973), N (MESH:D009584), CO (MESH:D002248), Cu (MESH:D003300), CO2 (MESH:D002245), C2H4 (MESH:C036216), CP (-), silver (MESH:D012834), C6H14N2O2 (MESH:D008239), Arg (MESH:D001120), Copper (II) acetate (MESH:C015092)
- **Mutations:** His at -1, His for 60, F200X

## Full text

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## Figures

7 figures with captions in the complete paper: https://tomesphere.com/paper/PMC12079362/full.md

## References

20 references — full list in the complete paper: https://tomesphere.com/paper/PMC12079362/full.md

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Source: https://tomesphere.com/paper/PMC12079362