Author Correction: Structure-property relationships of photofunctional diiridium(II) complexes with tetracationic charge and an unsupported Ir–Ir bond
Fangrui Zheng, Yuhong Yang, Siye Wu, Shunan Zhao, Yifan Zhu, Huimin Su, Jun-Feng Dai, Zeyin Yan, Lung Wa Chung, Keith Man-Chung Wong
Abstract
Genes, proteins, chemicals, diseases, species, mutations and cell lines named across the full text — each resolved to its canonical identifier and authoritative record.
Peer Reviews
No public reviews on file for this paper yet. If you reviewed it on a platform where reviews are public (OpenReview, ICLR, NeurIPS, ICML), you can paste yours below so the community can read it here.
Videos
No videos yet. Explain this paper in a talk, walkthrough, or lecture? Add one.
Taxonomy
TopicsMagnetism in coordination complexes · Metal complexes synthesis and properties · Organometallic Complex Synthesis and Catalysis
Correction to: Communications Chemistry 10.1038/s42004-022-00775-4, published online 23 November 2022
In the version of this article initially published, there were typographical errors in the first paragraph of the “Photophysical and electrochemical behaviours” section, where in the text now reading “Our TD-DFT (CPCM TD-B3LYP-D3//M06-L) calculations18 suggested that the low-energy absorption is mainly ascribed to metal–metal bond-to-ligand charge transfer (MMLCT) dσ(Ir–Ir) → π*(N^N^N ligand) transition with some mixing of dσ(Ir–Ir) → dσ*(Ir–Ir) character…,” dσ(Ir–Ir) instead appeared as “dπ(Ir–Ir)” in two instances and dσ*(Ir–Ir) instead appeared as “dπ*(Ir–Ir).” In the second paragraph of that section, in the text now reading “Collectively, together with the large Stokes shift, such luminescence of 1–3 is assigned to be originated from the triplet metal–metal bond-to-ligand charge transfer (3MMLCT), with some mixing of dσ(Ir–Ir) → dσ*(Ir–Ir) character…,” dσ(Ir–Ir) → dσ*(Ir–Ir) instead appeared as “dπ(Ir–Ir) → dπ*(Ir–Ir).” In the fourth paragraph of that section, in the text now reading “Upon reductive scan … with some σ*(Ir(II)–Ir(II)) character,” σ*(Ir(II)–Ir(II)) instead appeared as “π*(Ir(II)–Ir(II)),” and later in that paragraph, in the sentence now reading “The essentially irreversible nature of this reduction process is probably due to dissociation of the diiridium(II) framework, resulting from the population of σ*(Ir(II)–Ir(II)) orbital,” σ*(Ir(II)–Ir(II)) instead appeared as “π*(Ir(II)–Ir(II)).” The orbitals have been amended in the HTML and PDF versions of the article.