# Ultramicroporous Ionic Liquid-Supported Aerogel Composites

## TL;DR

This paper introduces a new material that efficiently captures low-concentration ammonia, which could be useful in fuel cells and confined environments.

## Contribution

The study introduces ultramicroporous ionic liquid-supported aerogel composites for enhanced ammonia capture and separation.

## Key findings

- UILACs achieved an NH3 capacity of 164.69 mg/g, 3.47 times higher than pure aerogel.
- UILACs showed NH3/H2 and NH3/N2 selectivity of 2460 and 10,474, respectively.
- UILACs maintained stable performance over ten adsorption–desorption cycles.

## Abstract

Recently, low-concentration ammonia (NH3) capture has attracted considerable attention for applications in ammonia–hydrogen fuel cells and confined spaces. The main objective of this study was to develop novel ultramicropore ionic liquid-supported aerogel composites (UILACs), designed to effectively expose the multiple hydrogen bonding sites of the ionic liquid through the constructed ultramicropore structure in order to capture and selectively separate low-concentration NH3. UILACs achieved a maximum NH3 capacity of 164.69 mg NH3/g absorbent at 25 °C and 0.10 MPa, which was 3.47 times higher than that of the pure aerogel. In breakthrough experiments with low NH3 concentrations (1000–10,000 ppm), UILACs exhibited exceptional NH3/H2 and NH3/N2 selectivity of 2460 and 10,474, respectively, at 1000 ppm NH3, values which are 31.5 and 22.1 times higher than the pure aerogel. These values significantly exceeded those of aerogels, owing to high hydroxyl ammonium ionic liquid (HAIL) loading, interactions between HAIL and NH3, and ultramicropores, as confirmed by density functional theory (DFT) calculations and isothermal analysis. Furthermore, UILACs maintained stable adsorption performance through ten adsorption–desorption cycles, demonstrating UILACs’ potentials for efficient NH3 capture and separation in energy applications.