Few-Layered MXene Modulating In Situ Growth of Carbon Nanotubes for Enhanced Microwave Absorption

TL;DR

This paper introduces a new composite material combining MXene and carbon nanotubes to improve microwave absorption performance.

Contribution

A novel strategy for in situ growth of carbon nanotubes on MXene to enhance microwave absorption properties.

Findings

The 2-Ni-MWCNTs/Ti3C2Tx composite achieves a reflection loss of −44.08 dB.

The composite has an effective absorption bandwidth of 1.52 GHz at 2.49 mm thickness.

The layered structure and regulation strategy improve impedance matching and electromagnetic parameters.

Abstract

MXene is widely used in the fields of microwave absorption and electromagnetic shielding to balance electromagnetic pollution with the development of communication technologies and human health, due to its excellent surface functional groups and tunable electronic properties. Although pure multilayered MXene has an excellent accordion-like structure, the weak dielectric loss and lack of magnetic loss result in poor microwave absorption performance. Here, we propose a strategy for the catalytic growth of CNTs by the electrophoretic deposition of adsorbed metal ions, leading to the successful preparation of Ni-MWCNTs/Ti3C2Tx composites with a “layer-by-layer” structure, achieved through in situ regulated growth of CNTs. By introducing dielectric–magnetic synergy to improve the impedance matching conditions, and by regulating the diameter of the CNTs to alter the electromagnetic parameters of Ni-MWCNTs/Ti3C2Tx, the 2-Ni-MWCNTs/Ti3C2Tx composite achieves the best reflection loss (RL) value of −44.08 dB and an effective absorption bandwidth of 1.52 GHz at only 2.49 mm thickness. This unique layered structure and the regulation strategy provide new opportunities for the development of few-layered MXene composites.

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