# The influence of thermal tempering on the fracture resistance, surface microstructure, elemental surface composition, and phase analysis of four heat-pressed lithia-based glass ceramic crowns

## TL;DR

This study examines how thermal tempering affects the strength and surface properties of four types of glass ceramic crowns used in dental applications.

## Contribution

The study reveals how different tempering temperatures influence the fracture resistance and microstructure of lithia-based glass ceramics.

## Key findings

- IPS e.max Press showed higher fracture resistance without tempering, while Lisi Press showed higher resistance with tempering.
- Thermal tempering significantly affected fracture resistance but did not change elemental composition or phase analysis.
- Zirconia oxide addition did not improve fracture resistance in lithium disilicate glass matrix.

## Abstract

This in-vitro study aimed to evaluate the impact of thermal tempering and ceramic type on the fracture resistance, surface microstructure, elemental surface composition and phase analysis of four heat-pressed glass ceramics.

A total of 84 glass-ceramic crowns were pressed and randomly allocated into four equal groups (n = 21) according to the ceramic type: Group (E): IPS e.max Press, Group (L): GC initial LiSi Press, Group (C): Celtra Press and Group (A): VITA Ambria. The crowns of each group were equally allocated into three subgroups (n = 7) regarding the subsequent thermal tempering temperature. Subgroup (T0): No tempering. Subgroup (T1): Tempering at 9% below pressing temperature. Subgroup (T2): Tempering at 5% below pressing temperature. Samples were tested for fracture resistance using a universal testing machine. A scanning electron microscope, X-ray diffraction, and Energy Dispersive x-ray analysis were utilized to disclose the microstructural features.

When there is no tempering, IPS e.max press showed a significant elevated fracture resistance (P-value = 0.002). There was an insignificant difference between other ceramics. While with tempering (T2) as well as (T1), Lisi press (L) showed a significant elevated fracture resistance. There was an insignificant difference between other ceramics (P-value = 0.004).

Incorporation of zirconia oxide into the lithium disilicate glass matrix did not show improvement in the fracture resistance. Thermal tempering procedure had significant effect on fracture resistance. Thermal tempering technique had no influence the elemental surface composition and phase analysis yet T2 samples showed changes in crystal size and orientation.