# Investigation of Piezoelectric Properties in Ca-Doped PbBa(Zr,Ti)O3 (PBZT) Ceramics

## TL;DR

This study explores how adding calcium improves the piezoelectric properties of a specific ceramic material.

## Contribution

The novel contribution is the significant enhancement of piezoelectric properties through small calcium doping in PBZT ceramics.

## Key findings

- Calcium doping increased the piezoelectric coefficient d31 significantly.
- Calcium-doped ceramics showed higher electrical permittivity across all temperatures.
- The material exhibited a notable remanent polarization.

## Abstract

The perovskite-structured materials Pb0.75Ba0.251−xCax(Zr0.7Ti0.3)O3 for x = 1 and 2 at.% were synthesized using the conventional mixed-oxide method and carbonates. Microstructural analysis, performed using a scanning electron microscope, revealed rounded grains with relatively inhomogeneous sizes and distinct grain boundaries. X-ray diffraction confirmed that the materials exhibit a rhombohedral structure with an R3c space group at room temperature. Piezoelectric resonance measurements were conducted to determine the piezoelectric and elastic properties of the samples. The results indicated that a small amount of calcium doping significantly enhanced the piezoelectric coefficient d31. The calcium-doped ceramics exhibited higher electrical permittivity across the entire temperature range compared to the pure material, as well as a significant value of remanent polarization. These findings indicate that the performance parameters of the base material have been significantly improved, making these ceramics promising candidates for various applications.