# Description of a Non-Canonical AsPt Blue Species Originating from the Aerobic Oxidation of AP-1 in Aqueous Solution

**Authors:** Damiano Cirri, Tiziano Marzo, Piero Mastrorilli, Valentina Petrelli, Stefano Todisco, Elvira De Giglio, Cristina Gellini, Marilena Ricci, Alessandro Pratesi, Luigi Messori

PMC · DOI: 10.3390/ijms25137408 · International Journal of Molecular Sciences · 2024-07-05

## TL;DR

Scientists discovered a unique blue chemical species formed when a specific compound is oxidized in water.

## Contribution

The paper identifies and characterizes a new non-canonical blue species resulting from the oxidation of arsenoplatin-1.

## Key findings

- A blue species named 'AsPt blue' forms during the aerobic oxidation of AP-1 in aqueous solution.
- The formation of AsPt blue involves complex processes revealed through a multi-technique approach.

## Abstract

The peculiar behavior of arsenoplatin-1, ([Pt(µ-NHC(CH3)O)2ClAs(OH)2], AP-1), in aqueous solution and the progressive appearance of a characteristic and intense blue color led us to carry out a more extensive investigation to determine the nature of this elusive chemical species, which we named “AsPt blue”. A multi-technique approach was therefore implemented to describe the processes involved in the formation of AsPt blue, and some characteristic features of this intriguing species were revealed.

## Linked entities

- **Chemicals:** arsenoplatin-1 (PubChem CID 137348900), AP-1 (PubChem CID 21119850)

## Full-text entities

- **Genes:** JUNB (JunB proto-oncogene, AP-1 transcription factor subunit) [NCBI Gene 3726] {aka AP-1}
- **Chemicals:** arsenoplatin-1 (MESH:C000717879), AsPt Blue (-)

## Full text

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## Figures

9 figures with captions in the complete paper: https://tomesphere.com/paper/PMC11242394/full.md

## References

28 references — full list in the complete paper: https://tomesphere.com/paper/PMC11242394/full.md

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Source: https://tomesphere.com/paper/PMC11242394