Addendum: Solution epitaxy of polarization-gradient ferroelectric oxide films with colossal photovoltaic current
Chen Lin, Zijun Zhang, Zhenbang Dai, Mengjiao Wu, Shi Liu, Jialu Chen, Chenqiang Hua, Yunhao Lu, Fei Zhang, Hongbo Lou, Hongliang Dong, Qiaoshi Zeng, Jing Ma, Xiaodong Pi, Dikui Zhou, Yongjun Wu, He Tian, Andrew M. Rappe, Zhaohui Ren, Gaorong Han

Abstract
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TopicsSmart Materials for Construction · Material Properties and Applications
Addendum to: Nature Communications 10.1038/s41467-023-37823-z, published online 24 April 2023
In this article, we reported a solution epitaxy of ferroelectric oxide films, focusing on single-crystal film of PbTiO_3_ on single-crystal Nb:SrTiO_3_ substrate. We would like to provide additional information to further support its epitaxy and single-crystal character by electron back-scattered diffraction (EBSD) and rocking curve analysis. Figure 1a presents a typical EBSD band contrast map of PbTiO_3_ film in a relatively large area, and the uniform color of the inverse pole figure (IPF) map in the Z direction (IPF Z in Fig. 1b) demonstrates that PbTiO_3_ film is a single crystal. Furthermore, the fullwidth at half maxima (FWHM) of the rocking curve (Fig. 1c) scanned around the (001) diffraction peak is only 0.028°, indicating a high-quality epitaxy of PbTiO_3_ film on the substrates.
Fig. 1 EBSD and rocking curve analysis of PbTiO3 film on (100) Nb(0.7wt%): SrTiO3 substrate. a EBSD band contrast image. b corresponding EBSD IPF Z direction color map. c rocking curve of PTO film (001) peak.
