# Borates expand their reduction power

**Authors:** Johannes Kreutzer

PMC · DOI: 10.1038/s42004-024-01171-w · Communications Chemistry · 2024-04-25

## TL;DR

A new borate compound can effectively reduce group 1 metal cations and CO2, offering a novel approach in chemical reduction.

## Contribution

A bipyridine-stabilized borate anion is introduced as a new reducing agent for challenging chemical reductions.

## Key findings

- The borate anion successfully reduces group 1 metal cations to their zero-valent forms.
- It is also effective in the two-electron reduction of CO2.

## Abstract

The chemical reduction of group 1 metal cations to their zero-valent species is challenging. Now, a bipyridine-stabilized borate anion joins the ranks of suitable reducing agents and also proves active in the two-electron reduction of CO2.

## Linked entities

- **Chemicals:** CO2 (PubChem CID 280)

## Full-text entities

- **Chemicals:** tetraphenyl borates (MESH:D013775), borate (MESH:D001881), carbon (MESH:D002244), Ge (MESH:D005857), pyridine (MESH:C023666), diphenyl borate (MESH:C035757), Lu (MESH:D008187), Li (MESH:D008094), K2CO3 (MESH:C037593), phenyllithium (MESH:C450681), THF (MESH:C018674), boron (MESH:D001895), Bipyridylboronium (-), CO2 (MESH:D002245), CuCl (MESH:C028419), CO (MESH:D002248), toluene (MESH:D014050), biphenyl (MESH:C010574)

## Full text

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## Figures

1 figure with captions in the complete paper: https://tomesphere.com/paper/PMC11045742/full.md

## References

2 references — full list in the complete paper: https://tomesphere.com/paper/PMC11045742/full.md

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Source: https://tomesphere.com/paper/PMC11045742