# Hydroxyl-terminated dendrimers with sulfonimide linkers as binders for metals of industrial significance

**Authors:** Khaleel ABU SBEIH, Mohammad AL HARAHSHEH

PMC · DOI: 10.55730/1300-0527.3641 · Turkish Journal of Chemistry · 2024-01-02

## TL;DR

This paper explores the use of hydroxyl-terminated dendrimers to bind metals important in industry and the environment.

## Contribution

The study introduces new hydroxyl-terminated dendrimers with sulfonimide linkers for selective metal binding.

## Key findings

- Dendrimers effectively bind Fe3+, Al3+, and UO22+ with industrial relevance.
- Dendrimers show selectivity for Fe3+ in mixtures with Al3+.
- Dendrimer synthesis was confirmed using a 1,3-diaminopropane core and sulfonimide linkers.

## Abstract

First- and second-generation hydroxyl-terminated dendrimers were prepared starting from a 1,3-diaminopropane core and sulfonimide linkers. A first-generation mesitylene-derived dendrimer was also prepared with the same terminals. The dendrimers were then reacted with Fe3+, Al3+, and UO22+ separately in order to apply the dendrimers for binding these metals, which have important industrial applications and pose environmental problems simultaneously. The prepared dendrimers were also shown to bind Fe3+ selectively from mixtures with Al3+.

## Linked entities

- **Chemicals:** Fe3+ (PubChem CID 29936), Al3+ (PubChem CID 104727), UO22+ (PubChem CID 14816), 1,3-diaminopropane (PubChem CID 428), sulfonimide (PubChem CID 17038)

## Full text

_Full body text omitted from this summary view._ Fetch the complete paper as Markdown: https://tomesphere.com/paper/PMC10965167/full.md

## Figures

8 figures with captions in the complete paper: https://tomesphere.com/paper/PMC10965167/full.md

## References

40 references — full list in the complete paper: https://tomesphere.com/paper/PMC10965167/full.md

---
Source: https://tomesphere.com/paper/PMC10965167