# Bubble Sensors for Temperature Measurements through a Colorimetric Approach

## TL;DR

This paper introduces a new temperature sensor using bubbles with thermochromic paint that changes color with temperature, suitable for hard-to-reach areas.

## Contribution

The novelty lies in using thermochromic paint-coated bubbles for passive, power-free temperature sensing in various applications.

## Key findings

- Combining red bubbles with blue thermochromic paint yields more accurate temperature readings.
- Colorimetric changes at 35°C are measurable and reproducible for specific bubble-paint combinations.
- The sensor's chromatic coordinates shift predictably with temperature changes.

## Abstract

This paper introduces an innovative sensor utilizing bubbles coated with thermochromic paint, aiming to facilitate temperature measurements in challenging-to-reach locations without the requirement of an external power source. The research conducted is innovative in terms of both methodology and application. The characterization of the thermochromic properties of paints was, in fact, performed using spectroradiometric measurements by selecting a temperature range useful for applications in various fields including preventive conservation. The study encompasses two main objectives: (1) analyzing the color characteristics of thermochromic paint and plastic resin that forms the bubbles, and (2) assessing a temperature sensor comprising a thermochromic paint-coated bubble subjected to temperature variations. The thermochromic paint exhibits reversible color modifications in response to temperature changes, making it an ideal candidate for applications of this nature. The color characterization phase involves measurements using a spectroradiometer to compare the spectral reflectance factor (SRF%) of the colored plastic resin spread on canvas with that of the inflated bubbles. The sensor characterization entails evaluating color changes of the thermochromic paint on the bubble surface with varying temperatures. Experimental results indicate that the combination of a red (R) bubble and blue (B) thermochromic paint produces quantifiable color variations suitable for the proposed applications, whereas the alternative combination under examination, namely a blue bubble and red thermochromic paint, yields less accurate results. Considering that for both thermochromic paints the color change temperature is 35 °C, it is possible to see how, for B bubble with R thermochromic paint, the chromatic coordinates change value: C* = 3.14 ± 0.14 and h = 289.54 ± 11.58 at room temperature, while C* = 2.96 ± 0.12 and h = 304.20 ± 12.17 at 35 °C. The same is true for R bubble with B thermochromic paint where C* = 25.31 ± 1.01 and h* = 285.05 ± 11.40 at room temperature, while C* = 20.87 ± 0.85 and h = 288.37 ± 11.53 at 35 °C. The study demonstrates the potential of the approach and suggests further investigations into reproducibility and expanded color combinations. The results provide a promising basis for future improvements in temperature monitoring with thermochromic bubble sensors.