# Optrode-Assisted Multiparametric Near-Infrared Spectroscopy for the Analysis of Liquids

**Authors:** Maria Giulia Delli Santi, Salvatore Castrignano, Marialuisa Capezzuto, Marco Consales, Patrizio Vaiano, Andrea Cusano, Gianluca Gagliardi, Pietro Malara

PMC · DOI: 10.3390/s24030729 · Sensors (Basel, Switzerland) · 2024-01-23

## TL;DR

This paper introduces a new compact method using optical fibers to analyze liquids by measuring multiple properties at once.

## Contribution

A novel optrode-assisted multiparametric near-infrared spectroscopy method is introduced for liquid analysis.

## Key findings

- A broadband radiation is encoded and distributed to multiple sensing units for simultaneous interrogation.
- The setup allows spectral readout via Fourier transform of each unit's output signal.
- Simultaneous measurement of absorption spectrum and refractive index of water–methanol solutions was demonstrated.

## Abstract

We demonstrate a sensing scheme for liquid analytes that integrates multiple optical fiber sensors in a near-infrared spectrometer. With a simple optofluidic method, a broadband radiation is encoded in a time-domain interferogram and distributed to different sensing units that interrogate the sample simultaneously; the spectral readout of each unit is extracted from its output signal by a Fourier transform routine. The proposed method allows performing a multiparametric analysis of liquid samples in a compact setup where the radiation source, measurement units, and spectral readout are all integrated in a robust telecom optical fiber. An experimental validation is provided by combining a plasmonic nanostructured fiber probe and a transmission cuvette in the setup and demonstrating the simultaneous measurement of the absorption spectrum and the refractive index of water–methanol solutions.

## Linked entities

- **Chemicals:** water (PubChem CID 962), methanol (PubChem CID 887)

## Full-text entities

- **Chemicals:** water (MESH:D014867), methanol (MESH:D000432)

## Full text

_Full body text omitted from this summary view._ Fetch the complete paper as Markdown: https://tomesphere.com/paper/PMC10857342/full.md

## Figures

3 figures with captions in the complete paper: https://tomesphere.com/paper/PMC10857342/full.md

## References

31 references — full list in the complete paper: https://tomesphere.com/paper/PMC10857342/full.md

---
Source: https://tomesphere.com/paper/PMC10857342