Dissolution of Metals (Cu, Fe, Pb, and Zn) from Different Metal-Bearing Species (Sulfides, Oxides, and Sulfates) Using Three Deep Eutectic Solvents Based on Choline Chloride

TL;DR

This paper explores using deep eutectic solvents to dissolve metals from different mineral forms, finding that sulfates dissolve much more effectively than oxides or sulfides.

Contribution

The study introduces three choline chloride-based deep eutectic solvents for metal dissolution from primary sources, highlighting their effectiveness on sulfates.

Findings

Metal dissolution from sulfates was two orders of magnitude higher than from oxides or sulfides.

Three DESs (reline, ethaline, glyceline) were tested for dissolving Cu, Fe, Pb, and Zn from various compounds.

Dissolution efficiency was strongly influenced by the metal-bearing species type.

Abstract

Nowadays, deep eutectic solvents (DESs) are seen as environmentally friendly alternatives with the potential to replace traditional solvents used in hydrometallurgical processes. Although DESs have been successfully applied in the recovery of metals from secondary sources, there is still innovative potential regarding DESs as green leaching agents applied in the recovery of metals from primary sources like polysulfide ores. This study aimed to evaluate the characteristics of DESs as solvents for some of the main metals present in typical polymetallic concentrates, like Cu, Fe, Pb, and Zn. Thus, three DESs based on choline chloride (ChCl) were prepared: 1:2 ChCl-urea (also known as reline), 1:2 ChCl-ethylene glycol (also known as ethaline), and 1:2 ChCl-glycerol (also known as glyceline). Then, dissolution tests at 30 °C were carried out with these DESs and different metal- (Cu, Fe, Pb, and Zn) bearing compounds (sulfates, oxides, and sulfides). According to the dissolution tests, it was found that the solubility of the studied metals (expressed as g of metal per Kg of DES) was dictated by the bearing species, reaching the dissolution of the metals from sulfates with values as high as two orders of magnitude higher than the metal solubility values for metal oxides and sulfides.

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