Particulate analysis of post-thermal runaway soot of Li-ion battery using X-ray computed tomography

TL;DR

This study uses Nano-CT imaging to analyze soot particles from lithium-ion battery thermal runaway, revealing core-shell carcinogenic structures that pose health risks.

Contribution

It introduces advanced 3D imaging for detailed particulate analysis, highlighting the detection of hazardous core-shell structures in battery soot.

Findings

Nano-CT effectively visualizes particle morphology and composition.

Core-shell structures contain carcinogenic materials.

Even minimal hazardous phases pose health risks.

Abstract

The microstructural characteristics of soot generated during thermal runaway events in lithium-ion batteries have been examined, with a focus on the associated health risks. X-ray computed tomography (Nano-CT) offers advanced 3D imaging for accurate analysis of particle shape, size, and distribution. Its primary benefit is the detection of core-shell structures that contain thin shell of carcinogenic materials. In contrast, traditional techniques like X-ray diffraction can only quantify the mass fraction of these hazardous phases, which is often minimal. Nevertheless, even a small mass fraction of carcinogenic materials on carbonaceous surfaces poses significant health risks when inhaled, potentially compromising internal organ function. This research underscores the need for a deeper understanding of particulate composition to inform safety regulations and respiratory protection measures.