Duality Between Chemical Potential Dynamics and Reaction-Diffusion Systems

TL;DR

This paper establishes a mathematical duality between chemical potential-driven phase-field theories and reaction-diffusion systems, unifying their descriptions of pattern formation in complex matter.

Contribution

It provides an explicit equation-level duality, linking these frameworks and resolving non-invertibility issues via an extended two-field description.

Findings

McRD systems encompass chemical-potential theories with conserved parameters.

The duality maps phase coexistence conditions to reaction turnover balance.

Derived a velocity law for traveling waves in nonreciprocal Cahn-Hilliard dynamics.

Abstract

Pattern formation in soft, active, and biological matter is described by two ostensibly distinct continuum frameworks: phase-field theories driven by chemical-potential gradients, and mass-conserving reaction-diffusion (McRD) dynamics governed by local interconversion kinetics. Here we establish a constructive, equation-level duality valid in the nonlinear, far-from-equilibrium regime. McRD is the broader class: every chemical-potential theory with conserved order parameters embeds as the slow dynamics on an attracting manifold of an McRD system; conversely, every McRD with attractive nullcline admits an exact chemical-potential representation in the fast-interconversion limit, with the constitutive relation set by the nullcline. The construction resolves the generic non-invertibility of the chemical-potential as a function of density in phase-separating regimes by embedding it as an attracting manifold in an extended two-field description with conserved total density. Gradient stiffness maps faithfully onto an intrinsic reaction-diffusion length set by the auxiliary field, yielding a diagonal-diffusion normal form whose interface profile matches the original Cahn-Hilliard model by construction. The duality yields an explicit dictionary for phase coexistence: the Maxwell equal-area construction is exactly equivalent to the reactive turnover-balance condition. It extends to weakly nonconservative dynamics, unifying reaction-arrested coarsening and mesa splitting, and to multicomponent theories with broken Maxwell symmetry. As a concrete payoff, the dual sharp-interface picture yields a closed-form velocity law for traveling waves in nonreciprocal Cahn-Hilliard dynamics, in quantitative agreement with simulations.