Geometrical Imperfections in a Digital Quadrupole Mass Filter: A Comprehensive Simulation Study in the First Stability Zone

TL;DR

This study uses comprehensive simulations to analyze how geometrical imperfections affect the performance of digital quadrupole mass filters, focusing on mass resolution and ion transmission in the first stability zone.

Contribution

It systematically investigates the impact of various geometrical imperfections on quadrupole mass filter performance, highlighting the importance of initial waveform conditions.

Findings

Radial asymmetries degrade resolution and transmission efficiency.

Octupole field components are introduced by geometrical imperfections.

Performance strongly depends on initial RF waveform state.

Abstract

Geometrical imperfections in quadrupole mass filters introduce higher-order field components that can significantly influence device performance, particularly under non-sinusoidal excitation. In this work, a comprehensive simulation study is carried out to investigate the effect of geometrical imperfections on the performance of a rectangular wave driven quadrupole mass filter operating in the first stability zone. Radial field distortions arising from controlled variations in rod geometry and position, including single rod radius variation, single rod displacement, diagonal rod radius variation, and diagonal rod displacement, are examined. These imperfections introduce octupole field components that distort the ideal quadrupolar field distribution. The influence of such distortions on key performance parameters, namely mass resolution and ion transmission efficiency, is systematically evaluated. The results show that the presence of radial asymmetry leads to a degradation of both resolution and transmission efficiency in all cases considered. Furthermore, the study reveals a strong dependence of mass filter performance on the initial state of the applied pulsed waveform, specifically whether the asymmetric rod pair is subjected to the high or low level of the RF pulse. These findings provide important insights into the tolerance limits of geometrical imperfections and their impact on the performance of pulsed wave driven quadrupole mass filters, which are relevant for the design and optimization of high-resolution digital mass filtering systems.