The evolution of C4H and c-C3H2 in molecular cores

TL;DR

This study maps and analyzes the evolution of small hydrocarbons C4H and c-C3H2 in star-forming regions, revealing their decreasing abundance ratios as molecular cores evolve, highlighting their role as precursors to complex organics.

Contribution

It provides new observational data and chemical modeling insights into the evolution of C4H and c-C3H2 in massive star-forming regions, emphasizing their changing abundances.

Findings

C4H and c-C3H2 detected mainly at the edges of H42 regions.

Abundance ratios of C4H/H13CO+ and c-C3H2/H13CO+ decrease with core evolution.

C4H and c-C3H2 are likely precursors to complex organic molecules.

Abstract

Linear C4H and cyclic c-C3H2, as small unsaturated hydrocarbons, are the key precursors to complex organic molecules and are critical components of the interstellar medium. We present on-the-fly mapping observations of C4H 9-8 lines, c-C3H2 2-1, H13CO+ 1-0, and H42 toward a sample of 22 massive star-forming regions using the IRAM 30m telescope. Our aim is to further explore the evolution of these carbon-chain molecules by combining observational results obtained in cold cores. We employed H13CO+ 1-0 and H42 as tracers to probe the positions of molecular cloud cores and ionised hydrogen regions (HII regions), respectively. One chemical model in particular, which includes gas, dust grain surface, and icy mantle phases for C4H and c-C3H2 molecules, was used to make comparisons with observed abundances. From mapping observations targeting 31 regions across 22 sources, C4H 9-8 (J = 19/2-17/2) and C4H 9-8 (J = 17/2-15/2) were detected in only 17 regions, while H13CO+ 1-0 and c-C3H2 2-1 were successfully detected in all 31 regions. We find that the emission of C4H 9-8 and c-C3H2 2-1 is concentrated at the edges of H42 emission regions. The C4H/H13CO+ and c-C3H2/H13CO+ relative abundance ratios range from 0.17 to 1.77 and 1.42 to 6.69, respectively, with a median C4H/c-C3H2 ratio of 0.13. By combining the observational results of cold cores, we find that C4H/H13CO+ and c-C3H2/H13CO+ ratios show a strong decreasing trend as molecular cores evolve. The decreasing trends in C4H/H13CO+ and c-C3H2/H13CO+ ratios imply that small unsaturated hydrocarbons can be consumed and converted into other organic molecules during the evolution of molecular cores. The spatial concentration of C4H and c-C3H2 emission at the edges of H42 regions further supports their role as precursors in the chemical pathways that lead to complex organic molecules in the interstellar medium.