The superite phase and phase transition inducing multiscale solidification microstructures and segregations in steels

TL;DR

This study reveals a new superite phase in steel solidification, showing a general liquid-superite-solid transition process that influences microstructure formation and segregation, challenging traditional alloy solidification understanding.

Contribution

It identifies a new superite phase and elucidates a general phase transition process during alloy solidification, providing insights into microstructure control in metals.

Findings

Discovered a superite phase with statistically oriented tiny structures.

Revealed a general liquid-superite-solid phase transition process.

Showed the impact of superite phase on microstructure and segregation formation.

Abstract

Based on classical concept, solidification of alloys is a direct transition from liquid phase to solid phase, by which dendrites and dendritic segregation are produced. Through in-situ and real time morphology observation and XRD test during solidification of three steels, a new superite phase featured as statistically oriented tiny structures was identified, and a general liquid-superite-solid phase transformation process is revealed. In the early solidification stage, the liquid alloys transit to dendrites composed of superite phase. Initiated from the boundaries of dendritic arms or dendrite grains, the superite phase transits to austenite grains within an initial dendritic arm, and expels solute elements to the residual superite phase. Mixed multi-phase microstructures are subsequently produced from the residual enriched superite phase. Here, although three steels exhibit different phase proportion and phase constitution in the superite-solid transition, they all follow above general transition mode. Multiscale microstructures and segregations are produced in the transition from superite to solid. These new findings change the basic understanding about the solidification of alloys, rediscover the formation mechanism on segregations and multiscale solidification microstructures, including dendrite pattern, solid dendritic arm, dendritic segregation, the mixed multi-phase microstructures, eutectic, inclusions and precipitate. These new findings are also crucial to the control of solidification microstructures and segregation in metals.