Confirmation of Fe I on MASCARA-5 b's Dayside Observed With EXPRES
James T. Sikora, Joe Llama, Rachael M. Roettenbacher, Elisabeth M. Brann, Jean-Michel D\'esert, Alex S. Polanski, Malena Rice, and Lily Zhao

TL;DR
This study confirms the presence of gaseous Fe I on MASCARA-5 b's dayside using EXPRES, revealing an inverted thermal atmosphere and potential wind-induced blueshift, advancing atmospheric characterization of ultra-hot Jupiters.
Contribution
First high-resolution optical spectroscopic confirmation of Fe I on MASCARA-5 b's dayside with detailed thermal and wind analysis.
Findings
Fe I detected with 5.5 sigma significance.
Thermal profile shows inversion with temperatures ~2000 K and ~4500 K.
Pre-eclipse blueshift of -3.2 km/s suggests atmospheric winds.
Abstract
MASCARA-5~b/TOI-1431~b is an ultra-hot Jupiter \citep[, , , ;][]{addison2021} orbiting a bright Am star (). Recent time-series observations obtained with PEPSI@LBT during the planet's post-eclipse phases have revealed Fe~{\sc i} emission lines indicative of a thermally inverted atmosphere. These observations demonstrate that MASCARA-5~b is well-suited to atmospheric characterization via emission spectroscopy, thereby motivating further follow-up observations covering additional orbital phases to constrain the planet's atmospheric chemistry, thermal structure, and dynamics. Here we present pre-eclipse time-series observations obtained with the high-resolution optical spectrograph EXPRES@LDT. Our analysis confirms the previous…
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