Mass-Transfer Control With Microbubbles in Highly Turbulent Decaying Flows

TL;DR

This study demonstrates that combining high turbulence with a tiny reduction in surface tension effectively controls bubble size in gas-liquid flows, enhancing mass transfer.

Contribution

It introduces a scalable method using minimal surfactant to tune bubble sizes in highly turbulent flows without altering turbulence characteristics.

Findings

Small surface tension reduction decreases average bubble size.

Turbulence statistics remain unchanged with surfactant addition.

Bubble size distribution becomes narrower with reduced surface tension.

Abstract

We hypothesize that combining extreme turbulence with a minute reduction in surface tension $\sigma$ (surface tension of the liquid) using surfactant provides a simple and scalable route for controlling micron scale bubble size in gas--liquid systems. To test this, we generate high-intensity turbulence using a multiphase pump [turbulent intensity $\ge 40\%$; Taylor Reynolds number $Re_\lambda=\mathcal{O}(10^3)$; bulk Reynolds number $Re=\mathcal{O}(10^5)$] feeding a straight duct, which produces a decaying turbulent flow where, without additives, bubble coalescence dominates and causes monotonic downstream growth in the mean diameter $d_\mathrm{avg}$ of the bubbles. This growth is governed by the turbulent dissipation rate $\varepsilon$. High-speed imaging, back-lit shadowgraph and particle shadow velocimetry (PSV) quantify bubble statistics ($d_\mathrm{avg}$, and the bubble-size distribution) and turbulence metrics (turbulent kinetic energy $k$, turbulence intensity $\mathcal{I}$, and dissipation rate $\varepsilon$). We then introduce a minute amount ($\sim 0.01\%$ critical micelle concentration) of additive that produces a slight reduction in $\sigma$, used here only as an interfacial tuning knob because the same change in surface tension can be achieved with non surface active agents. This small decrease in $\sigma$ enhances breakup, slightly suppresses coalescence, and makes smaller bubbles more breakup prone, resulting in reduced $d_\mathrm{avg}$ and a narrower bubble-size distribution. Turbulence statistics remain unchanged within experimental uncertainty, indicating that the effect arises entirely from interface rather than hydrodynamic changes. Overall, combining extreme turbulence with a minute reduction in surface tension offers a low complexity and tunable lever for setting bubble-size distributions and intensifying mass transfer in industrial multiphase flows.