The Convex-Analytic Structure of Thermodynamic Equilibrium: Pressure, Subdifferentials, and Phase Transitions
Abdoulaye Thiam

TL;DR
This paper develops a convex-analytic framework for thermodynamic formalism in dynamical systems, linking pressure, entropy, and phase transitions through duality and subdifferentials.
Contribution
It introduces a unified convex-analytic approach to thermodynamic formalism, encompassing classical and subadditive principles, with extensions to non-compact systems and applications to countable shifts.
Findings
Pressure is the Legendre-Fenchel transform of negative entropy.
Uniqueness of equilibrium states corresponds to differentiability of pressure.
First-order phase transitions are characterized by non-differentiability of pressure.
Abstract
We develop the convex-analytic structure of the thermodynamic formalism for continuous maps on compact metric spaces. The pressure functional is the Legendre-Fenchel transform of the negative entropy, and the biconjugate recovery of the entropy from the pressure establishes a complete duality. Equilibrium states are elements of the subdifferential of the pressure, uniqueness of equilibrium states corresponds to G\^{a}teaux differentiability, and first-order phase transitions correspond to non-differentiability. For systems with specification and H\"{o}lder potentials, the pressure is Fr\'{e}chet differentiable in the H\"{o}lder norm, and the second derivative of the pressure equals the asymptotic variance of the Birkhoff sums. We prove a universal variational principle that unifies the classical additive, the subadditive, and the relative variational principles through a single theorem…
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