Evaporative thermo-fluidics and deposition patterns in surface-active droplets

TL;DR

This study combines experiments and theoretical analysis to understand how surfactants influence evaporation, flow patterns, and deposition in droplets on different surfaces, revealing dominant Marangoni effects and complex contact line dynamics.

Contribution

It provides new insights into surfactant effects on evaporation and flow mechanisms, validated by experimental and theoretical approaches.

Findings

Surfactant concentration affects evaporation rate differently on hydrophilic and hydrophobic surfaces.

Marangoni solutal advection dominates other flow mechanisms during evaporation.

Contact line exhibits stick-slip behavior during droplet drying.

Abstract

We investigate the thermo solutal transport phenomena and deposition patterns during the evaporation of surfactant laden droplets experimentally and through theoretical scaling based analysis. Experiments were conducted using the sessile droplet configuration in the acrylic chamber for both hydrophilic and hydrophobic substrates. Infrared thermography and particle image velocimetry measurements were conducted during evaporation to illustrate the temperature and velocity distributions, respectively. Sodium dodecyl sulphate SDS surfactant molecules enhanced the evaporation rate with an increase in concentration for the hydrophobic surface. In contrast, the evaporation rate increased up to 0.5 CMC and then decreased for droplets on a hydrophilic substrate. The evaporation rates computed from the shadowgraphy imaging were explained using the average velocities obtained from the PIV analysis. It was found that advection within the droplet is strongly dependent on surfactant concentration and wettability. Further, the theoretically obtained Marangoni velocities were in close agreement with the experimental values. It was found that Marangoni solutal advection dominates other advection mechanisms, such as Marangoni thermal advection and buoyancy driven flow. However, surfactant crowding and viscous resistance with increasing surfactant concentration can dampen the increase in solutal advection. The surface tension and viscosity measurements were also conducted with variation in surfactant concentration to understand the suppression of advection by viscous forces. The computation of contact line velocities showed sudden fluctuations, illustrating stick slip behaviour during droplet drying, complementing microscopic visual observations.