Extraction of Effective Electromagnetic Material Properties for Rydberg Electrometer Vapor Cells from 10-300 MHz
D. Richardson, J. Dee, J. Yaeger, M. Viray, J. Marsh, B. Kayim, B. C. Sawyer, D. S. La Mantia, R. Wyllie, and R. S. Westafer

TL;DR
This study measures the complex permittivity and conductivity of vapor cells used in Rydberg electrometers across 10-300 MHz, enabling improved electromagnetic field correction and vapor cell design.
Contribution
It introduces a new measurement method and modeling approach to extract effective dielectric properties of vapor cells in the RF regime below 1 GHz.
Findings
Frequency-dependent RF dispersion and absorption observed.
Field reduction inside vapor cells quantified.
Validation with atomic measurements confirms results.
Abstract
Quantum sensors often consist of packaging, such as dielectric-based vapor cells and metallic electrodes, that reduces and spatially alters the locally observed electromagnetic fields. These effects have been well studied in the optical regime, and even in the RF regime over a few GHz. However, there have been few studies in the electrically small regime below 1 GHz. In order to account for or remove the effects of the packaging, more studies are needed across a broad range of frequencies. This paper reports on the complex permittivity and conductivity of several commercially available vapor cells used for Rydberg electric field sensing from 10-300 MHz. A new method using a stripline transmission measurement was performed and full wave electromagnetics modeling was used to extract the effective dielectric constitutive parameters from the vapor cells. Additionally, the field reduction…
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