Enhanced Kadowaki-Woods Ratio and Weak-Coupling Superconductivity in Noncentrosymmetric YPt$_2$Si$_2$ Single Crystals

TL;DR

This study reports the synthesis and characterization of noncentrosymmetric YPt2Si2 single crystals, revealing unconventional normal-state properties and weak-coupling two-gap superconductivity with a transition temperature of 1.67 K.

Contribution

First synthesis and detailed analysis of YPt2Si2 revealing its unconventional normal state and weak-coupling two-gap superconductivity.

Findings

No charge density wave transition in YPt2Si2 unlike LaPt2Si2.

Large Kadowaki-Woods ratio indicating unconventional normal state.

Superconductivity characterized by weak electron-phonon coupling and two-gap behavior.

Abstract

Superconductivity in noncentrosymmetric RPt2Si2 (R = rare earth) compounds exhibit a rich playground to explore the competition between different ground states, such as unconventional superconductivity, antiferromagnetism and charge density wave. Here, we report the successful single crystal synthesis of noncentrosymmetric YPt2Si2 superconductor, with a transition temperature Tc = 1.67 K, via Sn flux method. The high quality of the prepared single crystals was confirmed using powder and Laue XRD measurements. The superconducting and normal state properties are investigated using electrical transport and heat capacity measurements down to 0.5 K. In the normal state, unlike LaPt2Si2, no charge density wave transition is observed in YPt2Si2, as evidenced by electrical transport and specific heat measurements. A relatively large Kadowaki-Woods ratio and a linear temperature variation of the electrical resistivity in an extended temperature range of 50-300 K suggest an unconventional normal-state in YPt2Si2. The estimated superconducting parameters indicate that YPt2Si2 is a type-II superconductor with weak electron-phonon coupling. The temperature dependence of specific heat in the superconducting state can be explained reasonably well using an isotropic two-gap model. A positive curvature near Tc in the temperature variation of upper critical field also supports the two-gap superconductivity. First-principles DFT calculations suggest a BCS-like superconducting state driven primarily by d-electron contributions. The calculated electron-phonon coupling constant identifies the material as a weak-coupling superconductor, with the McMillan-Allen-Dynes formula yielding a Tc of 1.8 K. Additionally, we provide a comparative analysis of the superconducting and normal-state properties of YPt2Si2 and compositionally similar LaPt2Si2.